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◆图书简介
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图书编号： |
290101 |
| 图书名称： |
国外名校名著——化学和工程热力学(第三版）（英文影印版） |
| 作 者： |
Sandler |
| 定 价： |
75元 |
| 出版日期： |
2002年8月 |
| 装桢开本： |
16/平 |
◆内容介绍
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内容简介： |
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目 录： |
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NOTATION
CHAPTENR 1 INTRODUCTION
1.1 the Central Problems of Thermodynamics 1
1.2 A System of Units 3
1.3 The Equilibrium State 5
1.4 Pressure , Temperature , and Equilibrium 7
1.5 Heat , Work , and the Conservation of Energy 12
1.6 Specification of the Equilibrium State ; Intensive and Extensive Variables; Equations of State 15
1.7 A Summary of Important Experimental Observations 18
1.8 A Comment on the Development of Thermodynamics 20
CHAPTER 2 CONSERVATION OF MASS AND ENERGY 22
2.1 A General Balance Equation and Conserved
Quantities 23
2.2 Conservation of Mass 27
2.3 Conservation of Energy 30
2.4 The Thermodynamic Properties of Matter 43
2.5 Applications of the Mass and Energy Balances 51
2.6 Conservation of Momentum 75
2.7 The Microscopic Equations of Change for Thermodynamics and Fluid Mechanics (Optional) 76
CHAPTER 3 ENTROPY: AN ADDITIONAL BALANCE
EQUATION 89
3.1 Entropy: A New Concept 90
3.2 The Entropy Balance and Reversibility 97
3.3 Heat, Work , Engines, and Entropy 103
3.4 Entropy Changes of Matter 112
3.5 Applications of the Entropy Balance 115
3.6 Liquefaction 128
3.7 Power Generation and Refrigeration Cycles 132
3.8 The Thermodynamics of Mechanical Explosions 154
3.9 The Microscopic Entropy Balance (Optional) 163
CHAPTER 4 THE THERMODYNAMIC PROPERTIES OF
REAL SUBSTANCES 175
4.1 Some Mathematical Preliminaries 175
4.2 The Evaluation of Thermodynamic partial Derivatives 179
4.3 The Ideal Gas and Absolute-Temperature Scales 194
4.4 The Evaluation of Change in the Thermodynamic Properties of Real Substances Accompanying a Change of State 195
4.5 An Example Involving the Change of State of a Real Gas 219
4.6 The Principle of Corresponding States 225
4.7 Generalized Equations of State 238
4.8 The Third Law of Thermodynamics 242
4.9 More About Thermodynamic Partial Derivatives (Optional ) 243
CHAPTER 5 EQUILIBRIUM AND STABILITY IN ONE-
COMPONENT SYSTEMS 260
5.1 The Criteria for Equilibrium 260
5.2 Stability of Thermodynamic Systems 265
5.3 Phase Euqilibria : Application of the Equilibrium and Stability 272
5.4 The Molar Gibbs Free Energy and Fugacity of a Pure Component 279
5.5 The Calculation of Pure Fluid-Phase Equilibrium: The Computation of Vapor Pressure from an Equilibrium of State 295
5.6 The Specification of the Equilibrium Thermodynamic State of a System of Several Phases : The Gibbs Phase Rule for a One-Component System 303
5.7 Thermodynamic Properties of Phase Transitions 307
CHAPTER 6 THE THERMODYNAMICS OF
MULTICOMPONENT MIXTURES 324
6.1 The Thermodynamic Description of Mixtures 324
6.2 The Partial Molar Gibbs Free Energy and the Generalized Gibbs-Duhem Equation 333
6.3 A Notation for Chemical Reactions 337
6.4 The Equations of Change for a Multicomponent System 340
6.5 The Heat of Reaction and a Convention for the Thermodynamic Properties of Reacting Mixtures 349
6.6 The Experimental Determination of the Partial Molar Volume and Enthalpy 354
6.7 Criteria for Phase Equilibrium in Multicomponent Systems 364
6.8 The Criteria for Chemical Equilibrium, and Combined Chemical and Phase Equilibrium 368
6.9 The Specification of the Equilibrium Thermodynamic State of a Multicomponent, Multiphase System ; the Gibbs Phase Rule 373
6.10 Some Concluding Remarks 377
CHAPTER 7 THE ESTIMATION OF THE GIBBS FREE
ENERGY AND FUGACITY OF A
COMPONENT IN A MIXTURE 388
7.1 The Ideal Gas Mixture 388
7.2 The Partial Molar Gibbs Free Energy and Fugacity 392
7.3 The Ideal Mixture and Excess Mixture Properties 396
7.4 The Fugacity of Species in Gaseous , Liquid , and Solid Mixtures 406
7.5 Several Correlative Liquid Mixture (Activity Coefficient ) Models 414
7.6 Two Predictive Activity Coefficient Models 428
7.7 A Corresponding States Principle for Mixtures ; The Pseudocritical Constant Method 437
7.8 The Fugacity of Species in Nonsimple Mixtures 444
7.9 Some Comments on Reference and Standard States 451
7.10 A Combined Equation-of-State—Excess Gibbs Free Energy Models 452
7.11 Electrolyte Solutions 455
7.12 Concluding Remarks 461
CHAPTER 8 PHASE EQUILBRIUM IN MIXTURES 478
8.1 Vapor-Liquid Equilibria Using Activity
Coefficient Models 478
8.2 Vapor-Liquid Equilibria Using Equations of State 518
8.3 The Solubility of a Gas in a Liquid 536
8.4 The Solubility of a Liquid in a Liquid and Vapor-Liquid-Liquid Equilibrium 550
8.5 The Solubility of a Solid in a Liquid , Gas , of Supercritical Fluid 575
8.6 The Partitioning of a Solute Among Two Coexisting Liquid Phases; The Distribution Coefficient 586
8.7 Freezing-Point Depression of a Solvent Due to the Presence of a Solute ; the Freezing Point of Liquid Mixtures 598
8.8 Osmotic Equilibrium and Osmotic pressure 603
8.9 The Phase Behavior Modeling of Chemicals in the Environment 608
8.10 The Phase Behavior of Solid Mixtures 614
8.11 Concluding Remarks 623
CHAPTER 9 CHEMICAL EQUILIBRIUM AND THE
BALANCE EQUATIONS FOR CHEMICALLY
REACTING SYSTEMS 630
9.1 Chemical Equilibrium in a Single-Phase System 630
9.2 Heterogeneous Chemical Reactions 663
9.3 Chemical Equilibrium When Several Reactions Occur in a Single Phase 676
9.4 Combined Chemical and Phase Equilibrium 683
9.5 The Balance Equations for a Tank-Type Chemical Reactor 691
9.6 The Balance Equations for a Tubular Reactor 699
9.7 Overall Reactor Balance Equations and the Adiabatic Reaction Temperature 702
9.8 The Thermodynamics of Chemical Explosions 711
9.9 Introduction to Electrochemical Processes 717
9.10 Coupled Chemical Reactions 727
APPENDIXES 744
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