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◆图书简介
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图书编号： |
210048 |
| 图书名称： |
国外名校名著——化工热力学导论（第6版）（英文影印版） |
| 作 者： |
J.M.Smith |
| 定 价： |
78元 |
| 出版日期： |
2002年5月 |
| 装桢开本： |
16/平 |
◆内容介绍
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内容简介： |
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目 录： |
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List of Symbols
Preface
1 INTRODUCTION
1.1 The Scope of Thermodynamics
1.2 Dimensions and Units
1.3 Measures of Amount or Size
1.4 Force
1.5 Temperature
1.6 Pressure
1.7 Work
1.8 Energy
1.9 Heat
2 THE FIRST LAW AND OTHER BASIC CONCEPTS
2.1 Joule’s Experiments
2.2 Internal Energy
2.3 The First Law of Thermodynamics
2.4 Energy Balance for Closed Systems
2.5 Thermodynamic State and State Functions
2.6 Equilibrium
2.7 The Phase Rule
2.8 The Reversible Process
2.9 Constant-V and Constant-p processes
2.10 Enthalpy
2.11 Mass and Energy Balances for Open Systems
3 VOLUMETRIC PROPERTIES OF PURE FLUIDS
3.1 PVT Behavior of Pure Substances
3.2 Virial Equations of State
3.3 The Ideal Gas
3.4 Application of the Virial Equations
3.5 Cubic Equations of State
3.6 Generalized Correlations for Gases
3.7 Generalized Correlations for Liquids
4 HEAT EFFECTS
4.1 Sensible Heat Effects
4.2 Latent Heats of Pure Substances
4.3 Standard Heat of Reaction
4.4 Standard Heat of Formation
4.5 Standard Heat of Combustion
4.6 Temperature Dependence of △H
4.7 Heat Effects of Industrial Reactions
5 THE SECOND LAW OF THERMODYNAMICS
5.1 Statements of the Second Law
5.2 Heat Engines
5.3 Thermodynamic Temperature Scales
5.4 Entropy
5.5 Entropy Changes of an Ideal Gas
5.6 Mathematical Statement of the Second Law
5.7 Entropy Balance for Open Systems
5.8 Calculation of Ideal Work
5.9 Lost Work
5.10 The Third Law of Thermodynamics
5.11 Entropy from the Microscopic Viewpoint
6 HERMODYNAMIC PROPERTIES OF FLUIDS
6.1 Property Relations for Homogeneous Phases
6.2 Residual Properties
6.3 Residual Properties by Equations of State
6.4 Two-Phase Systems
6.5 Thermodynamic Diagrams
6.6 Tables of Thermodynamic Properties
6.7 Generalized Property Correlations for Gases
7 APPLICATIONS OF THERMODYNAMICS TO FLOW PROCESSE
7.1 Duct Flow of Compressible Fluids
7.2 Turbines(Expanders)
7.3 Compression Processes
8 PRODUCTION OF POWER FROM HEAT
8.1 The Steam Power Plant
8.2 Internal-Combustion Engines
8.3 Jet Engines; Rocket Engines
9 REFRIGERATION AND LIQUEFACTION
9.1 The Carnot Refrigerator
9.2 The Vapor-Compression Cycle
9.3 The Choice of Refrigerant
9.4 Absorption Refrigeration
9.5 The Heat Pump
9.6 Liquefaction Processes
10 VAPOR/LIQUID EQUILIBRIUM: INTRODUCTION
10.1 The Nature of Equilibrium
10.2 The Phase Rule . Duhem’s Theorem
10.3 VLE: Qualitative Behavior
10.4 Simple Models for Vapor/Liquid Equilibrium
10.5 VLE by Modified Raoult’s Law
10.6 VLE from K-Value Correlations
11 SOLUTION THERMODYNAMICS: THEORY
11.1 Fundamental Property Relation
11.2 The Chemical Potential and Phase Equilibria
11.3 Partial Properties
11.4 Ideal-Gas Mixtures
11.5 Fugacity and Fugacity Coefficient: Pure Species
11.6 Fugacity and Fugacity Coefficient: Species in Solution
11.7 Generalized Correlations for the Fugacity Coefficient
11.8 The Ideal Solution
11.9 Excess Properties
12 SOLUTION THERMODYNAMICS: APPLICATIONS
12.1 Liquid-Phase Properties from VLE Data
12.2 Models for the Excess Gibbs Energy
12.3 Property Changes of Mixing
12.4 Heat Effects of Mixing Processes
13 HEMICAL-REACTION EQUILIBRIA
13.1 The Reaction Coordinate
13.2 Application of Equilibrium Criteria to Chemical Reactions
13.3 The Standard Gibbs-Energy Change and Equilibrium Constant
13.4 Effect of Temperature on the Equilibrium Constant
13.5 Evaluation of Equilibrium Constants
13.6 Relation of Equilibrium Constants to Composition
13.7 Equilibrium Conversions for Single Reactions
13.8 Phase Rule and Duhem’s Theorem for Reacting Systems
13.9 Multireaction Equilibria
13.10 Fuel Cells
14 TOPICS IN PHASE EQUIL IBBIA
14.1 The Gamma/Phi Formulation of VLE
14.2 VLE from Cubic Equations of State
14.3 Equilibrium and Stability
14.4 Liquid/Liquid Equilibrium(LLE)
14.5 Vapor/Liquid/Liquid Equilibrium(VLLE)
14.6 Solid/Liquid Equilibrium(SLE)
14.7 Solid/Vapor Equilibrium(SVE)
14.8 Equilibrium Adsorption of Gases on Solids
14.9 Osmotic Equilibrium and Osmotic Pressure
15 THERMODYNAMIC ANALYSIS OF PROCESSES
15.1 Thermodynamic Analysis of Steady-State Flow Processes
16 INTRODUCTION TO MOLECULAR THERMODYNAMICS
16.1 Molecular Theory of Fluids
16.2 Second Virial Coefficients from Potential Functions
16.3 Internal Energy of Ideal Gases: Microscopic View
16.4 Thermodynamic Properties and Statistical Mechanics
16.5 Hydrogen Bonding and Charge-Transfer Complexing
16.6 Behavior of Excess properties
16.7 Molecular Basis for Mixture Behavior
16.8 VIE by Molecular Simulation
A Conversion Factors and Values of the Gas Constant
B Properties of Pus Species
C Heat Capacities and Property Changes of Formaation
D Representative Computer Programs
D.1 Defined Functions
D.2 Solution of Example Problems by Mathcad
E The Lee/kesler Generalized-correlation Tables
F Steam Tables
F.1 Interpolation
G Thermodynamic Diagrams
H UNIFAC Method
I Newton’s Method
Author Index
Subject Index
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